محمد مجدى محمد ضيف الله
مدرس
Synthesis of Novel Gemini Surfactants Based on Succinic Acid and Their Application as Inhibitors for Carbon Steel Corrosion
Journal of Bio- and Tribo-Corrosion • 2020
معلومات البحث
المؤلفون
Mona A. El‑Etre,Samar Abdelhamed , Mohamed Deef Allah
الكلمات المفتاحية
Organic synthesis · Gemini surfactant · FTIR · NMR · C-steel · Corrosion inhibition
المجلة العلمية
Journal of Bio- and Tribo-Corrosion
الناشر
Springer
المجلد
6
العدد
Not Available
الصفحات
127
publication.type
International
رابط البحث
Not Available
المواد المرفقة
Not Available
الملخص
Three nonionic Gemini surfactants were synthesized based on succinic acid. The structures of the synthesized surfactants
were characterized using FTIR and 1H NMR spectra. The physical properties such as surface tension ( ), critical micelle
concentration (CMC), surface pressure (effectiveness) ( CMC ), maximum surface excess concentration (Γmax), and minimum
surface area occupied by one molecule (Amin) were calculated. The inhibitive power of the surfactants toward acid corrosion
of carbon steel was obtained using weight loss and electrochemical techniques. The morphology of the carbon steel surface
was examined by atomic force microscope. It was found that all the three surfactants act as good inhibitors for steel corrosion
in the acidic medium. The inhibition efficiency increases with increasing surfactant concentration and exposure time.
The inhibition action was attributed to the adsorption of the surfactant’s molecules on the steel surface. It was found that the
adsorption process is spontaneous and obeys Langmuir adsorption isotherm. A mechanism was proposed for the inhibition
action based on the obtained results.
were characterized using FTIR and 1H NMR spectra. The physical properties such as surface tension ( ), critical micelle
concentration (CMC), surface pressure (effectiveness) ( CMC ), maximum surface excess concentration (Γmax), and minimum
surface area occupied by one molecule (Amin) were calculated. The inhibitive power of the surfactants toward acid corrosion
of carbon steel was obtained using weight loss and electrochemical techniques. The morphology of the carbon steel surface
was examined by atomic force microscope. It was found that all the three surfactants act as good inhibitors for steel corrosion
in the acidic medium. The inhibition efficiency increases with increasing surfactant concentration and exposure time.
The inhibition action was attributed to the adsorption of the surfactant’s molecules on the steel surface. It was found that the
adsorption process is spontaneous and obeys Langmuir adsorption isotherm. A mechanism was proposed for the inhibition
action based on the obtained results.
