Asmaa Ali
Lecturer
Enhanced corrosion protection of copper alloy in 2.0 M HNO3 solution using expired solo sept, slim-lax and well derm drugs
International Journal of Electrochemical Science • 2024
Publication Information
Authors
R.N. Felaly, M. Alfakeer, Asmaa A.I. Ali, Salih S. Al-Juaid, Elsayed M. Mabrouk,
A.Y. El-Etre, Doaa F. Seyam, M. Abdallah
Keywords
Inhibition
Copper
Expired Drugs
EIS
Potentiodynamic
Adsorption
Journal
International Journal of Electrochemical Science
Publisher
Elsevier B.V
Volume
19
Issue
Not Available
Pages
100657
publication.type
International
Paper Link
Not Available
Supplementary Materials
Not Available
Abstract
Three expired drugs, Solo Sept (SS), Slim-lax (SL), and Well Derm (WD), have been tested as corrosion inhibitors
for corrosion of copper alloy (C10100) in 2.0 M HNO3 solution. Three experimental methods such as weight loss
measurements, potentiodynamic polarization (PDP), and electrochemical impedance spectroscopy (EIS) were
applied in this study. These expired drugs function as effective inhibitors, according to the experimental fndings.
The effcacy of inhibition rises with increasing drug concentration and falls as temperature rises. From PDP, the
examined drugs that worked as mixed-type inhibitors. EIS measurements showed a remarkable increase in the
charge transfer resistance and decreases in the capacity of the double layer of the corroding copper in 2.0 M
HNO3 solution with increasing drug concentration. The inhibition power of these drugs was interpreted in term
of its adsorption on the C10100 surface according to Langmuir isotherm. The inverse effect of temperature on
drug effciency as well as the small negative values of ΔG◦ads (-20.84, -20.52 and -20.51 kJ/mol) for SS, SL and
WD respectively, supports the physical adsorption of drugs on the C10100 surface. All results showed consistency
with IE order (SS > SL > WD). The adsorption thermodynamic functions were estimated. The corrosion inhibition performance of SS was confrmed through SEM (scanning electron microscope) and FTIR
for corrosion of copper alloy (C10100) in 2.0 M HNO3 solution. Three experimental methods such as weight loss
measurements, potentiodynamic polarization (PDP), and electrochemical impedance spectroscopy (EIS) were
applied in this study. These expired drugs function as effective inhibitors, according to the experimental fndings.
The effcacy of inhibition rises with increasing drug concentration and falls as temperature rises. From PDP, the
examined drugs that worked as mixed-type inhibitors. EIS measurements showed a remarkable increase in the
charge transfer resistance and decreases in the capacity of the double layer of the corroding copper in 2.0 M
HNO3 solution with increasing drug concentration. The inhibition power of these drugs was interpreted in term
of its adsorption on the C10100 surface according to Langmuir isotherm. The inverse effect of temperature on
drug effciency as well as the small negative values of ΔG◦ads (-20.84, -20.52 and -20.51 kJ/mol) for SS, SL and
WD respectively, supports the physical adsorption of drugs on the C10100 surface. All results showed consistency
with IE order (SS > SL > WD). The adsorption thermodynamic functions were estimated. The corrosion inhibition performance of SS was confrmed through SEM (scanning electron microscope) and FTIR
