Mohammed Ahmed El Sayed Kassem
Professor
The Impact of Ultrasonication on SDS‑stabilized Silver Nanoparticles as a Probe for Trace Determination of Diaveridine
Plasmonics • 2023
Publication Information
Authors
40- Mohammed A. Kassem, Hesham H. El‑Feky
Keywords
Diaverdine HCl · Ultrasonication · Surface plasmon resonance · Silver nanoparticles · Spectrophotometry
Journal
Plasmonics
Publisher
SpringerLink
Volume
Not Available
Issue
Not Available
Pages
Not Available
publication.type
International
Paper Link
Open Link
Supplementary Materials
Not Available
Abstract
In this work, a new spectrophotometric ultrasonicated method was applied for the determination of diaverdine HCl (DIA). The
process was based on a controlled preparation of silver nanoparticles stabilized with sodium dodecyl sulphate (SDS-AgNPs),
and then the obtained solution was subjected for a definite time to ultrasonication, which in turn increased the absorbance of
surface plasmon resonance (SPR), at λmax = 395 nm, by 50%. The analyte (DIA) was added to freshly sonicated SDS-AgNPs,
and the DIA concentration was monitored with respect to the decreasing SPR absorption spectra. The obtained results and
the mechanism of silver nanoparticle aggregation due to DIA addition were confirmed using the data obtained from FT-IR
and TEM measurements. A spectrophotometric determination of DIA was valid with a linear range of 0.1–1.5 μg mL−
1 with
R2 and relative standard deviation of 0.992 and 1.72%, respectively. The developed method was successfully applied for the
monitoring of DIA in spiked bovine milk samples and a veterinary drug sample.
process was based on a controlled preparation of silver nanoparticles stabilized with sodium dodecyl sulphate (SDS-AgNPs),
and then the obtained solution was subjected for a definite time to ultrasonication, which in turn increased the absorbance of
surface plasmon resonance (SPR), at λmax = 395 nm, by 50%. The analyte (DIA) was added to freshly sonicated SDS-AgNPs,
and the DIA concentration was monitored with respect to the decreasing SPR absorption spectra. The obtained results and
the mechanism of silver nanoparticle aggregation due to DIA addition were confirmed using the data obtained from FT-IR
and TEM measurements. A spectrophotometric determination of DIA was valid with a linear range of 0.1–1.5 μg mL−
1 with
R2 and relative standard deviation of 0.992 and 1.72%, respectively. The developed method was successfully applied for the
monitoring of DIA in spiked bovine milk samples and a veterinary drug sample.